US 7,550,381 B2
Contact clean by remote plasma and repair of silicide surface
Xinliang Lu, Fremont, Calif. (US); Chien-Teh Kao, Sunnyvale, Calif. (US); Chiukin Steve Lai, Sunnyvale, Calif. (US); and Mei Chang, Saratoga, Calif. (US)
Assigned to Applied Materials, Inc., Santa Clara, Calif. (US)
Filed on Jul. 18, 2005, as Appl. No. 11/183,999.
Prior Publication US 2007/0015360 A1, Jan. 18, 2007
Int. Cl. H01L 21/44 (2006.01)
U.S. Cl. 438—655  [438/4; 438/742; 257/E21.582; 257/E21.483] 14 Claims
OG exemplary drawing
 
1. A method for forming a metal silicide, comprising:
positioning a substrate having an at least partially oxidized metal silicide surface disposed thereon in a processing chamber;
cleaning one or more oxidized regions of the at least partially oxidized metal silicide surface with reactive species to remove the oxidized regions to provide an altered metal silicide surface; and
exposing the altered metal silicide surface to one or more silicon-containing compounds at conditions sufficient to recover the metal silicide surface, wherein the one or more silicon-containing compounds and the reactive species are different, wherein cleaning the one or more oxidized regions comprises:
supporting the substrate having the at least partially oxidized metal silicide surface disposed thereon in a vacuum chamber;
generating the reactive species from a gas mixture within the chamber;
cooling the substrate within the chamber;
directing the reactive species to the cooled substrate to react with the native oxides thereon and form a film on the at least partially oxidized metal silicide surface; and
heating the substrate within the chamber to vaporize the film.